What I meant by "sealed" is simply to screw the lid on to preclude particulate contamination (dust, etc) and additional moisture absorption. The water vapor present in the head-space of the container is fairly irrelevant, the act of opening and closing the container many times will only add up to a small fraction of water being absorbed into the
PG.
When I search the literature for oxidation of propylene glycol, I am finding references to catalysts, high temperatures, and strong oxidizing agents such as potassium permanganate.
I believe it unlikely that the oxygen contained at room temperature in the head-space of a container of
PG is a sufficiently strong oxidizer to affect
PG under normal storage conditions.
The reason you'll find expiration dates on some materials is simple: They're required to have one.
Here's an example. HPLC grade water is a very pure grade of water used as a "mobile phase component" in high pressure liquid chromatography. Even if kept unopened, guess what, it has an expiration date. (wouldn't want it absorbing water, I guess)
(and BlueSun, if you can't have fun with the WalMart folks, what's the use of living?)
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