walrus, planetofthevapes is correct. Just connect the GND pin to the negative of the battery. If I remember correclty this is for your double 18650 mod, so you should be able to connect ground to the flash light body.
The tab has no electrical connection, but is used for heat dissipation. Check out page 9 of the spec sheet from TI, it talks about thermal design. It says:
The chip has thermal shut down protection, so if the temp rises too much, it will not turn back on until the temp goes back down to 20 degrees celcius.
Richie G, that is the wrong chip. Similar, but the chip in question does not have the center leg cut.