Hi Andria
ECF'ers decided a loooong time ago that it was best to let batteries rest after coming off the charger. Here's the Library article authored by Rolygate :
http://www.e-cigarette-forum.com/forum/ecf-library/129569-rechargeable-batteries.html
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Rest batteries after charging
One commonly-reported factor in almost all the incidents we hear of where batteries failed violently while in use is that they were taken directly off the charger and then used immediately, at which point they failed.
Because of this, we think it may be a good idea to rest batteries after charging them. This advice will not be found in the usual 'reference bibles' on batteries, but we see more and different reports than others. Therefore we now advise:
Do not use batteries directly after charging them. Use a battery or batteries you previously charged, and that have rested for several hours. This is especially important if using a stacked pair for higher voltage, as statistically the risk is far higher."
also, from Battery University, I think the reason why is they're agitated from charging:
Recognizing Battery Capacity as the Missing Link – Battery University
"A battery requires few hours of rest to regain equilibrium..... Loads and charge currents distort the voltage further, but one of the largest challenges is the flat discharge voltage curve of some lithium-based systems. This is especially evident with lithium-iron phosphate."
So, it might be ok to take a battery off the charger to put in a flashlight or something like that, but where ecig type batts are concerned I've always let the batts rest.
Hope this helps