I wish I could find the article about specific battery chemistries, but... a rechargeable battery (generically speaking)
may lose a very small percentage of charge, sometimes referred to as a "self-discharge rate"... literally, overnight. The age and use profile of a battery will have a bearing on this self-discharge rate.
The i2 (and most other intelligent chargers in the same category), senses the battery as being less than fully charged and, for the 5 minutes or so by your count, brings it back to full charge.
Nitecore i2 review.