You want to make sure you always use protected batteries.
Using a multimeter is nice bc you can check how much your batteries have left. Try to throw them back on the charger when they have about 25% left, they will last longer that way.
Having a digital multimeter also allows you to check the ohms of your attys and cartos.
Batteries have a certain amount of charge cycles in them. Normally toward the end of their life a battery wont hold a charge as well, last as long, etc. Thats when I get a new one. Thats whats nice about using a PV that uses non-proprietary batteries. Their cheap enough that you can always just get a new one