The Provari uses a patented Accuset microprocessor said to be military grade. It is designed to provide the same user-set voltage output to the juice delivery attachment throughout the duration of the battery life within 1% accuracy. It monitors the battery voltage and atty ohm rating continuously and adjusts itself accordingly to provide the set voltage. If you are looking for voltage accuracy for a consistant vaping experience, then the Provari is for you. It uses a single battery. It has a built-in voltage meter and ohm meter, both that provide measurements under true load (most accurate).
I can't speak about the Reo Grand from personal experience. I do know that it costs more than the Provari for a unit that is not as well constructed. Voltage is set by a turning wheel, so it is pretty much done "by taste". No voltage or resistance meter. It utilizes 2 stacked batteries to be able to do variable voltage, so there is a cost factor there in the long run of needing 2 batteries vs one with the Provari.
Unless you are looking for a bottom feeder specifically or just like the box mod form factor, the choice seems like a no brainer to me.