18650 = 18mm diameter, 65mm long.
26650 = 26mm diameter, 65mm long.
A 26650 will generally have more capacity and will give you more
vape time between charges. However, the difference isn't as big as the difference in volume might lead you to think because the 18650 size is where battery manufacturers have done the most development and thus tend to have the most energy per unit of size.