They should perform the same......its the same atomizer. Although the longer airpath of the bigger tank may give a slightly different hit than that of the smaller tank. At least thats the way it is with my Kayfuns. Same performance, slightly different feel to the draw.
It's the same chamber size and airflow so should be the same. One just has more juice on board. The distance the vape has to travel may make a small amount of difference. I would kill myself with a 3 ml tank. I go through juice in my 6ml too fast as it is and refilling is a bit of a PITA.
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