(Most?) chargers that can do LiFePO batteries cannot auto-detect them for whatever reason (that is above my pay grade so I can't tell you why) and must be manually set into LiFePO mode when using those batteries, even when it can tell the difference between Ni-Cd and Li-ion batts automagically.
LFP batteries charge to 3.6V/cell.
Li-Ion charge to 4.2V/cell.
Just a side note...LFP batteries are Li-Ion. What most people mean when they say Li-Ion though are the IMR, INR and ICR batteries we vape with instead of LiPo (which are also Li-Ion) or LFP.
(Most?) chargers that can do LiFePO batteries cannot auto-detect them for whatever reason (that is above my pay grade so I can't tell you why) and must be manually set into LiFePO mode when using those batteries, even when it can tell the difference between Ni-Cd and Li-ion batts automagically.
All a charger knows about a battery is its voltage. It then makes an assumption. 1-ish volt - it's a NiMH/NiCD. 3-ish volts - it's some kind of li-ion. It won't know which kind since any kind of li-ion (LiFe included) can be 3-ish volts.
Charging an IMR with the LiFe program won't damage the battery. It simply won't get fully charged.
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