With a PARALLEL box (both positives connected to the same place, both negatives connected to the same place), you do get DOUBLE AMPS
The samsung 25rs are only 20 amps, in a parallel box with 40amp-capable-wiring you will get a 40 amp limit. I run a parallel box with samsung 25r's myself at .09 ohms all day every day and its great, and keeps the batteries well within their limits
With a SERIES box (one battery positive connected directly to the other battery's negative), you get DOUBLE VOLTAGE, but the SAME AMPS AS ONE battery. That means you'd still have a 25 amp limit, but a .3 coil on a series box would pull way more amps than a .3 coil on a parallel box.The way to remedy this is to just build higher resistance.
I also run a series box at .4 ohms (8.4 volts because series) and its just as hard-hitting as my .09 ohm build (at 4.2 volts). Both of these setups are around the 150 watt area and are not pushing the batteries anywhere near their limits
EDIT: DO NOT MIX CHARGED AND UNCHARGED BATTERIES IN A PARALLEL BOX, if the voltages are too different, one battery will charge the other, and if youre firing a powerful build with this happening, you can seriously damage your batteries. That being said, parallel boxes naturally try to drain both batteries evenly and if you use a married pair, they will never give you a problem with draining batteries at different rates