I think the same characteristics that give PG good TH can also make 100 percent PG a bit harsh on my tongue, leaving a sort of tingly feeling. Some VG in the mix makes it smoother and for me, a fuller feeling vapor (may just be because you can see it better).
When you try different ratios, note that the nicotine level also affects TH (nicotine adds a bit of TH). And I think the flavors can make a noticeable difference too. Just like other flavored items, you'll probably feel more TH from things like cinnamon and mint, a bit less from some tobacco flavors, and even less from mellow flavors like cream and peach. And the flavor difference also depend on the mixer and whose flavorings they are using etc.