Methyl Salicylate = Methyl Sal = Oil of Wintergreen = Salicylic Acid, Methyl Ester. It contains ~90% salicylate by weight.
Aspirin = acetylsalicylic acid. It contains ~76% salicylic acid by weight.
Methyl salicylate (oil of wintergreen) (Salicylic adic, methyl ester) can be dangerous stuff. The Wikipedia article (via it's source) on the stuff stating that a single teaspoon contains 7 grams of salicylate is wrong, it's more like ~5.3 grams (assuming a teaspoon is 5 mL), still considerable.
Methyl Salicylate is often used internally (wintergreen lifesavers, etc). One 0.05 mL drop of methyl salicylate contains ~53 mg of salicylate (a single low-dose 81 mg aspirin contains ~62 mg salicylate). It is also used externally in pain rubs. I've seen it present at 30% in these products. It can and has been lethal via overuse in external ointments.
If 4 drops (0.2 mL) oil of wintergreen were used to make 10 mL of an eliquid, the salicylate concentration would be ~21 mg/mL. So vaping 1 mL of this (and assuming full absorption of the oil by the body) would give one about a third of an 81 mg low-dose aspirin worth of salicylate. As stated in a previous post, this represents a pretty good wintergreen hit.
The chemist in me says go for it if you like it, but try to keep it down to a few drops per 10 mL of eliquid. I suspect using too much in an eliquid would be a fairly self-limiting exercise.