IMO, as the batteries are married to each other and not the mod, it is good practice to rotate which slot the battery occupies in the mod to rotate which gets the worse wear equally.
Hmmm...
If the pair is married but is used in a variety of devices, then my theory about not caring whether they're rotated makes even more sense. One cell of a married pair would have a 50/50 chance of making it into slot A in every device it's used in. Discharge, recharge and insert into a different mod and it's 50/50 again. Meanwhile, the first mod gets a freshly charged pair without regards to who gets slot A or B.
Increase the numbers of both married pairs and two-cell devices and the business of keeping up with which cell of which pair goes into slot A of which device gets rather complicated.
It's good practice to have at least two cells for every battery slot you will have occupied at any given time. So if you have two two-cell devices, you're keeping up with a double rotation of eight cells. If you have three two-cell devices, then you're keeping up with a rotation of 12 cells.
If you're ambivalent about rotating, then the more devices you have the more likely an even distribution occurs. If you only have one device, life is simple.