Sounds odd. The native minimum output voltage of the TI is 5V. A booster basically needs to boost, output voltage must be higher than input voltage... correct?I'm not sure about the diode. I've seen where a diode has been shown in-line with the atomizer to lower bottom end voltage range, but that also lowers the top end range. You won't want to do that since you're looking for maximum voltage output.
The diode will lower the entire range, the maximum can still be far higher than it needs to be.