Peanut Butter Cup from FreedomSmokeUSA is on of my favorite juices. You might want to give it a try, but taste is very subjective, so I can't guarantee that it will work for you.
Since I DIY, I can't answer your direct question, however, I give you an observation due to your "spot on" comment: Most PB Cup type of candy has at least two things that enhance the PB/Choc flavor: Sugar and SALT. Now, EM may help you in the sugar dept. But the salt..... that's a tough one for e-juice, and is the part I have missed the most in my DIY choc/PB experiments. You wouldn't want to add salt to e-juice. So, I'll watch this thread to get answers too. I wonder what the vendors do about such things.......
Good luck in your search. (watching with interest)
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