Ratsey, I am not an expert with chem or precision measuring by any means. I think that unless you are mixing micro-batches of 1ml or less, the volume contained in a syringe needle (of the gauges we would be using) is not even measurable on the scale of "I or anyone else can detect the difference".
Pouring VG is probably the most inaccurate thing we do, because of it's thickness. Warming it will help. For batches of 30 ml or so, a 5ml syringe with the needle removed is a handy and accurate way to measure and dispense VG. It fits into the mouth of the bottle I store VG in, and without a needle, can slurp up a syringe-full in two seconds. Because a syringe (a positive displacement device) definitely empties it out, you don't have a thick layer of VG hanging onto the walls of a graduated cylinder, and is more accurate. For larger batches, I use a graduated cylinder for VG, and just let it drip for a long time (burrette clamp/stand to hold it, so I can do something else).
Pipette pumps and pipetting syringes can be even more accurate for small amounts.
I mix for other people, so I try to take more care in measuring than if it was just for myself.