If you want DIY juice, you may find VG in any pharmacy. Just ask for pure Vegetable Glycerin or pure Glycerol. Be sure they are USP grade. On the contrary, if you are looking for an eliquid supplier to purchase 100% VG based juices, you can find many in the US as ECOpure, or you may ask other suppliers such as Tasty Vapor if they may make 100% VG for you.
Yes, Walmart has VG. Wilson in the cake decorating section, and Humal (I think that was the brand) in the Pharmacy area near the hand lotion.
I bought the Humal. It is very thick, so you will need a large whole dripper to get it to drip out. I ended up just using the actual lid that comes with it and filled my 3ml half full.
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