I thought this was right down your ally. The minute I saw the question I had one thought: BK
amplitude is the power/strength of a signal, the height of the peaks and valleys of waves in the ocean for example. Frequency is the number of times the amplitude peaks in a moment of time. the substance which the power is being put thru is either conductive or insulative. A conductor is used to allow the power ( lets use volts/electricity) to travel thru it ( a wire) metals are better conductors since they usually have the outer electron shell incomplete ( not filled to the 8) and will easily pickup and release extra electrons pushed into its electron orbit area by voltage applied. An insulator has a full or nearly full electron orbit shell and is resistive to picking up or releasing electrons thus inhibiting voltage flow. So, an insulator is a really good resistor. A resistor is a material that is an insulator mixed with a conductor, for example clay and carbon powder. Or a resistor is a conductor designed to minimize the flow of electrons via mechanics, for example a thin wire is a good resistor.
okaayyy to tackle the above, to create Thermonic emmisions one needs heat, enuf heat to excite the material being heated to vibrate fast enuf at the molecule level along with a voltage gradient high enuf to shake electrons free from the orbit. The higher the voltage ( amplitude) increases the potential to shake loose some electrons, the frequency needs to be fast enuf ( the waves close together) to not allow the electrons to settle down ( think of shooting a gun, you pull the trigger and bang the gun jumps and you move a little) a low amplitude low frequency source would be like shooting a 22 once a second. A hi amplitude hi frequency source would be like shooting a full automatic 50 caliber machine gun which fires at 10 times a second ( for example) for as long as the gun is fed ammo( its strong enuf to move you backwards and push you down). Once you have the electron loose and its being kept loose, it finds its way to the positive ( anode) pole. If there are any contaminates in the container, the electron will want to attach its self to it and then off both the contaminate and electron go towards the anode, thus darkening it. A hi voltage and high frequency has a better chance of creating thermonic emissions. As I mentioned before, noble gasses are decent insulators... up to a point, once that point is reached, the gas no longer is insulative but now conductive in a plasma state ( this is why neon glows). To get to that point the voltage needs to be strong enuf not only to shake loose an electron and let it carry over to another molecule, but to keep it suspended for enuf time to gain enuf power to release it when the electron does fall back into place. When it falls back into place, the energy it was holding onto is released as a photon... thus the glowing neon.