Assuming you would leave these plugged in all the time it would be on charge all the time, or on and off repeatedly every time you start and kill your engine.
( depending on how you socket is wired ) Probably already has one in it, li-ion is probably only battery that could handle that kind of abuse.
VWFringe, please be careful using those.... Im sure you know that they are unprotected. I use this PCB for 3.7V Li-ion Battery to make them a lot safer.
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