Drop size varies according to various factors like the dropper size and the liquid's viscosity - 20 to 25 drops seems an average but you should check it, if it needs accuracy for a mix. It's hard to get it perfect for a small amount of liquid, a large quantity is much easier. Small DIY mixes might involve the use of 3 different sizes/types of drop so they are hard to get precisely right: per 1ml, maybe 16 drops of base with a dropper, 3 drops of flavor 1 with a different dropper, 1 drop of flavor 2 from a small flavor dripper bottle, and 1 'microdrop' from a syringe of a strong flavor like menthol, for example. Impossible to get that precise, 10ml is much more accurate as you can measure the drops per ml for each of the various dropper types.
A small syringe is a good tool for measuring this as you can get the very last drop out of a small container after 20 drops from each type of dropper or dripper bottle. You need a couple of syringes and pipettes for DIY, plus a selection of empty bottles, 10ml dark glass with droppers and 5ml small plastic dripper bottles are good.