Tons of other threads already up to learn about this but in a simple explanation:
Battery play depends on how the unreg box is wired
Series (one Battery positive side up, other positive down) - double the voltage. You're basically stacking batteries and so the mod would be pushing around 7.5-8 volts.
Parallel (both positives up) - pushes a normal voltage output (4.2v), double the mah (battery life), can't tell you much about the amp limit since I've never gotten too into parallel box mods and seen numerous debates on whether the amp limit doubles or not but it does feel safer to fire a .12 build on a mod with two batts compared to a single 18650 mech lol