The Samsung 25R should be good up to 100watts occasionally in the iStick100w. Yes, rotating the position of a married pair in a mod is an extra safety measure, even rotating them each cycle on the charger of which bay helps as well. My Sigelei150w and IPV3, pull the batteries out to put them on my charger, the battery closest to the control chip generally has the most draw off it, most the power pulls and flows through it, though these are series config mods, example batt1 in bay 1, batt2 in bay 2, put them on the charger batt1 reads 3.5v, batt2 reads 3.6v, next time in the mod and go to recharge them, batt2 in bay 1, batt1 in bay2, batt2 reads 3.5v and batt2 reads 3.6v. So yes it is good practice to not over stress one particular battery in a married pair, balance their usage cycles as best you can extends their life cycle as well as increases safety. For say month down the road, not rotating the batteries, batt1 could be 3.9v compare to batt2 being 4.1v on a fresh charge, weak link where potential failure will be is at batt1.
I've go 6 sets of married batteries, and label all my batteries of date of first charge, then with married pairs, bottom cap I mark 1A/1B, 2A/2B, etc so I can keep track of oldest to newest, and how many charges each pair have had.