Voltage and wattage are often misunderstood by new vapers.
Wattage is the power (heat, sweet spot) that your PV (battery and atomizer) generates. Wattage = Voltage (of your battery) squared divided by Resistance (Ω) of your atomizer [P=V[SUP]2[/SUP]/R]. If you're not good at math, don't worry, use this easy calculator:
Online Conversion - Ohm's Law Calculator
Of course, if you own a VW (variable wattage) device, you don't really need this calculator because your device will do the math for you.
The wattage you want, especially at the beginning of your vaping career, should be somewhere between 4.5 and 8.5 Watts. Anything lower than 4.5 watts may not vaporize your juice properly and will not produce enough warmth and vapor. Anything above 8.5 watts increases the risk of burning the filler in your cartomizers (if you're using them) and even some juices, especially the delicate ones.
There are, of course, other variables, like eliquid and JDD (juice delivery devices) that you're using on your batteries. Seven watts on a filler type cartomizer may feel different than the same 7 watts on a fillerless clearomizer or a dripping atomizer. The same is true for different eliquids; tobaccos, chocolate and coffees generally require more wattage (heat), while fruit and other delicate flavors do better with less heat. Everyone's sweet spot is different--those are just very general guidelines.
Experiment and you'll find your own bliss in no time!
The chart below is a good guide to safe vaping, even though some think it's a bit conservative.