I have already described 20 years old glycerin, but let me repeat it.
I have in my lab 20 year old 0.5 L clear bottle of glycerin. It was opened 20 years ago. Was opened again and again. Now it is about 0.5 full. Stored on a shelf under bright light (not sunlight). It is of reagent grade (a bit higher than USP), but
I would not try to vape it. For example reagent style alcohol (200 proof) is much worse in taste than cheap vodka - it was just cleaned out of different type of impurities. OK, back to glycerin. It is still clear, no odor, may be (just may be) a little bit more sticky than fresh one (I use it only as a hand lotion, when skin is too dry).
I do not recommend to save VG for 20 years, I just wanted to say its shelf life should be quite long. And in a freezer, with nic, it should be really long, longer than that of nicotine anyway.