You PURCHASE the nic in a 10% concentration or less. Doing it yourself (if you just want the nic part in PG) is very expensive and probably dangerous. In fact, you could probably afford a 20 years supply purchased before you managed to get all the proper stuff and safety gear to do everything the "right" way. (<--- Crap shoot estimate, to make a point.)
So basically, the extraction process doesn't matter.
There are threads on making nic-juice from tobacco, but that's for flavor and other things (like WTAs) too. To isolate the nic is probably a PITA. That's why there's even trace amounts of "other things" in our nic base. I'm no chemist, but it just doesn't make sense (or cents) to do it yourself unless the nic base supply dries up.
Just order a case of nic at 100 mg strength and store it in the basement freezer. You can check into glass bottles for storage too. Use gloves if you have to transfer 100 mg stuff. PG and VG are likely to remain available. As are flavorings for candy making.
Just
