Isn't Acrolein is a severe pulmonary irritant? I think as many people that vape VG, there would be some people wondering why it was killing their throat and lungs. I seriously doubt a properly wicked atty is actually hitting 536 degrees in a normal "vaping" burn. Normal being burns no longer than 8 seconds. I used an infrared thermometer at work to see how hot the atty hit. I actually did not think this would be useful was mostly just playing around with the thermometer. When the atty had juice on it the thermometer read 180F, when it wasn't wet it topped the thermometer out at 250F at 6 seconds. I burnt them both for 8 seconds. Your atty isn't going to hit 536F in less than 10 secs. It's not like your atty becomes superheated to 500F+ the second or even in the first 8 seconds of hitting the button. Even if your atty hit the proper temps to convert the VG, the actual VG would take even longer to hit that temp and as little as you have on the atty at any given point, it would vaporize away before achieving this conversion. There is just to many holes in this for it to happen in an everyday situation. Theoretically it may be possible if you had an atty that could take a very long burn, just filled it with an insane amount of VG, and most likely would need to be done on 6V+ device. If your goal is to create Acrolein, I think you would have a better shot using something other than an e-cig device.
So no you cannot use your e-cig as a device to produce a chemical warfare agent and profit from it.