Maybe someone else knows better, but I thought the molecular structure of both PG and VG were hydrophilic.
Yup.
Vegetable Glycerin is obtained by adding alkalies to fats and fixed oils. In the case of this certified organic glycerin, the source is soy bean oil. Glycerin is a soothing, humectant which draws moisture from the air to the skin. Glycerin is an emollient, which makes the skin feel softer and smoother, reduce rough feeling, cracking and irritation. Glycerin has a high hydrophilic (water) factor and a low lipophilic (fat) factor. Nontoxic, nonirritating and nonallergenic. Very sweet syrup, about 0.6 as sweet as sugar.
Therefore, the answer is NO. The water will NOT evaporate. The juice will absorb even more water from the air. Then again, if the air is zero relative humidity, evaporation may occur.
Edit - Actually, I think the proper term is hydroscopic rather than hydrophilic