For 2000 mAh
batteries - easily the 1 amp switch position. Any battery 1000 mAh or lower you definitely want to put the switch in the 500 mAh position. Most of my
batteries fall to extremes anyway so there isn't a lot to figure out. My 18650's are all 2 amp or higher so 1 amp position. Any of my 14500, 16350's etc. are 900 mAh or less - so all those get the .5 position.
ETA: The bottom line is you never put more charging current into a battery than it's rated ouput. Charging a 2 amp capacity battery at only 500 mA - not a problem - it just might take longer. But charging an 800 mAh battery at 1 amp - PROBLEM.
The "0" position is for using the WPII 2 as a charging device. With the charger unplugged put an 18650 battery in slot 1, connect the device you want to charge to the USB port.