Stacking batteries is unsafe. Or, I should say it's not the safest use of them in high drain devices like APV's. The Vamo has redundant circuitry in it to prevent short circuits and it monitors temperature in the device. If battery problems occur, the device shuts itself off.
However, that circuitry is not the world's finest, most expensive or most reliable.
What can happen is that you stack two batteries with different charge states and different actual capacities. The one with the greater charge remaining can attempt to charge the other, which can cause either to go into thermal runaway. One going thermal means both batteries go thermal and a potential catastrophe can occur inside that sealed metal tube.
The two grey 800mAh 18350 batteries that come in some Vamo kits are risky for use in standalone mode and should never be stacked. Those are unprotected ICR cells and have an unsafe chemistry. While the Vamo has the circuitry to prevent most incidents from getting out of hand, you are again back to trusting cheap electronics to prevent personal injury or property damage due to a fire or an explosion.
You should get high quality batteries. AW IMR's are the best available in 18350 configuration. Efest also makes decent 18350's. Those are the ones you want, but I wouldn't stack those, either.