Set the charger to 4.2v, which is the fully charged voltage of a 3.7v nominal Li-ion battery like you bought.
BTW, that charger is not particularly good as chargers go.
Here's a review of it by a good reviewer. If you want to skip the technical stuff scroll down to the conclusion. The safety concern is the charger doesn't fully stop charging when the
batteries are full. Overcharging these
batteries will at the least make them wear out fast, at worst can cause them to burn or explode. It also does a slow charge, making it harder to always be there and awake when it's charging.
Never leave this charger on overnight.
Also, those batteries are 20 amp max continuous, not 35A.