By unprotected, do you mean IMR batteries or lithiums with no protection circuit.
In general, it's not good to leave them too long. Anything is possible.
But any half-decent chargers have a protection circuit against over-charging, protected batteries have a circuit against overcharging and IMR's can't really explode in any case, although they can overheat enough to burn or melt anything they're around.
If they don't overcharge in the first place, like the lights change green, then the charging circut in the charger is working and it's unlikely to suddenly quit working during the same session. If the light never turns green, and the batteries don't overheat or explode, then the protection circuit in the battery has done its job.
So, leaving them in the charger doesn't cause anything to fail and lead to an explosion. But if they're in the charger and something, two things in the case of protected batteries, fail, there could be a problem. Highly unlikely, but it's good practice to take them out as soon as possible.
Most incidents are caused by cheap cords on the chargers or a cheap charger (like an ego charger) and a cheap protection circuit in the battery. If you have a good charger and good quality batteries, it's highly unlikely you'll have a problem.
You might also look into getting a cheap timer to plug the charger into. Then the power will be automatically cut and you don't have to worry about forgetting to take them out.