It's a personal choice. There's nothing wrong with pre-mixing your base. I do it and find it speeds the process when making test samples. Some complain it's not very accurate but I find it works quite well for me. When I mix my large batches of ADV's I always mix my base fresh but test batches I premix just to speed up the process.
As far as freeze-re-freeze-freeze there is a downside to it because when you do that air gets into the bottle which can oxidize NIC fast and the thawing process can allow water condensation to build up in the bottle which is not good for NIC either. What I do is rebottle my nic (I
buy it by the liter) into 120ml bottles and once removed from the freezer it becomes my working NIC that I then store in a cool dark draw and use it for my every day mixing.