Coloration of unflavored nic juice is primarily from oxidation of nic to nicotine-N-oxide, which is yellow/brown. It takes almost zero amounts of this to yellow a nic juice. I have seen the pink color too, but strangely (or not) it has only been from low-nic unflavored I have made with VG.
Us chemists are trying to figure out what it is, but it seems to pose zero threat. I am leaning towards it being the N-oxide, but maybe higher conc than that which makes it yellow, or binding with the VG in a different way than normal thus creating the color...but it only happens once in a while with my DIYs, and most of my low-nic unflavoreds I've made do not do this. I have never seen it in high-nic juice. If it is the N-oxide, and it very likely is, it poses not problems that we know of, and its conc is still extremely low, with 99% of the nic still intact unless the juice has been open and is very old. Eventually nic exposed to the air will all react to form N-oxide.
You might find this thread informative:
http://www.e-cigarette-forum.com/forum/diy-e-liquid/86000-word-about-nicotine-purity-storage.html
You will get to see the chemists debating, changing their minds, correcting each other, and all the normal things that happen in real chemistry. We do not have all the answers, but we are always learning and improving our understanding of this relatively new form of nic (e-juice).
Us chemists are trying to figure out what it is, but it seems to pose zero threat. I am leaning towards it being the N-oxide, but maybe higher conc than that which makes it yellow, or binding with the VG in a different way than normal thus creating the color...but it only happens once in a while with my DIYs, and most of my low-nic unflavoreds I've made do not do this. I have never seen it in high-nic juice. If it is the N-oxide, and it very likely is, it poses not problems that we know of, and its conc is still extremely low, with 99% of the nic still intact unless the juice has been open and is very old. Eventually nic exposed to the air will all react to form N-oxide.
You might find this thread informative:
http://www.e-cigarette-forum.com/forum/diy-e-liquid/86000-word-about-nicotine-purity-storage.html
You will get to see the chemists debating, changing their minds, correcting each other, and all the normal things that happen in real chemistry. We do not have all the answers, but we are always learning and improving our understanding of this relatively new form of nic (e-juice).