Simple answer, yes.
In parallel you add the amps and in serial you add the volts.
The circuit will draw from both
batteries. If one battery has a higher voltage it will have a heavier draw and the voltage will eventually even out. If you do something stupid, like pair a 6 amp easy fire with a 30 amp Sony, and the circuit wants 30 amps then it will draw 15 from each and cause a problem, but we're not that stupid.
Also, for a mod with a charger, charging works well. The less full battery will take more of the current until they are equal so things will be good.
In series there are some problems. The weaker battery will be called on to do more work, heating it up and making it weaker, causing it to do more work, and get even hotter, etc. If the bats are in series they need to work the same. Start off with a fresh pair and keep them together and check the voltage when you take them out and when you finish charging them. When the voltage differs it is time to split them up and start with a new pair.
When charging in series the weaker battery will charge first and then the charging current will continue to flow through it increasing heat and weakening it further.
Some of the new 100 watt regulated devices have the
batteries in series and that is a problem as far as I can tell.