What kind of batteries are you going to stack? Protected ICR or safer chemistry IMR?
What brand of batteries are you going to use? There's a very wide difference between brands, and this distinguishes the higher quality batteries from the lesser quality batteries. Do you know which brands are considered to be the best (and safest)?
Stacking batteries is generally frowned upon in the vaping community. You have to ask yourself is the added risk in battery safety worth the results. A single large battery is always going to be safer than two smaller stacked batteries. There was a time when stacking batteries in mechanical mods for higher voltage was "the thing". Then regulated mods came about and made it possible to experience higher voltage without the risks of battery stacking. Now its sub-ohm coils for mechanical mods. There are those who state that you can get the same results from micro-coils without the risks involved with sub-ohm vaping.
In some mods, you can fit two 18350's when the mod is configured for an 18650. This boosts the voltage output from 3.6V to 7.2V which means more vapor. Yay.

BUT, you probably should never do this.
Unless you are familiar with matching batteries, you are only endangering yourself and others. Sometimes,
just because you can doesn't mean you should.
You may think, "Hey, laptops have multiple batteries in them, why can't my e-cig?" Laptop batteries are specifically designed for stacking and are paired for use at the factory. When using un-matched batteries, they will discharge and provide current at different rates. This means one battery will continuously take more of the stress than the other.
You may not notice any trouble at the start, but as the batteries age with use the problem will become more severe. Push the batteries a bit further and now you've entered the realm of
thermal runaway (see pics below). Downside being that one battery entering thermal runaway will push the other battery into thermal runaway. Now you have two small, flaming explosives only inches from your face. Save your teeth and home, don't stack batteries .
If you really feel the need for higher voltage, just get a regulated VV/VW mod. It will have built-in protective circuitry to keep you reasonably safe where a mechanical mod will not.




