So...
1) What we're doing is more accurately called "aging".
Ok, so let's call it that.
2) Heat, light and air degrade nicotine.
When I use nicotine, I mix at very low nic levels (3 or less, using 48 mg VG based nicotine solution), so I notice very little if any "degradation" in my mixes. I aim for just enough nicotine to give that little "bump" for the flavors to ride upon. If I can taste the nic over or competing with the flavors, it's too much for me. When I was vaping 12mg premixed some of the cheaper stuff I got had very pronounced "degradation, where it would change from light amber to an almost bloody reddish brown. By that point it was way too harsh and horrible tasting to vape, even if diluted with 0 nic of the same flavor. That nasty "degraded nicotine" taste just broke right through the flavors and dominated. I'd add that all this happened in sealed bottles stored in a cool dark place.
Anyway, I always referred to that as oxidation, due to the color change, but I've noticed that some of my 0 nic mixes darken too. It's obviously not the VG/PG, which means it's the flavoring changing color.
I guess my biggest question is, in a 0 nic mix, why does the flavor change, or more specifically, why does it become
better? If I was mixing lemonade for example, a little shaking and stirring would get it to its best state flavor wise. From there, the aging process would
degrade the flavor. So why is it the opposite with eliquid. Is it like, the flavoring needs time to propagate fully into the VG/PG? Seems that way. Unaged liquid fresh off the scale tends to have a chemical bite. I suspect there's some sort of "degassification" going on where those unwanted chemical elements either evaporate or are diluted into the carriers. How does it all work??
Cripes, now I've got visions of little flavor molecules floating around, reaching out, embracing...
bonding with each other while a clock spins in the background. I really should have paid more attention in Chemistry class!