There's a great sticky on charging lithium battery's in tips&tricks area- you can also read up on battery university. Charging overnight is generally regarded as a bad idea. From what I can tell, letting a lithium cell sit on a charger past 4.2v, puts unneeded stress on the battery, besides it is better to charge periodically, lithium cells do not need to be saturated. 14500s are cheap, buy more and rotate them. I had a rather expensive problem overcharging some aw imrs, it resulted in frying a pretty nice mod. Always measure your voltage with a multimeter after charging. Better safe than sorry.