If you're looking for a true vanilla bean flavor as in, from the pod, it's going to be a long, hard search

.
I have a number of vanilla flavors and none of them truly replicate the flavor you'd get from a vanilla bean pod. This includes Capella's Simply Vanilla, FlavourArt's Tahity & Bourbon Vanilla's and a small sample of The Flavor Apprentice's Vanilla. They're not bad, but they're not, IMO, true vanilla flavors.
I've also tried a number of vanilla extracts. The issue with most extracts is that, at least in the US, to be a true extract, it has to contain at least 35% alcohol and the alcohol has to be of a high enough proof to prevent the vanilla from being able to rot. Vodka is often not high enough proof, so they have to go with something stronger, such as PGA, or Pure Grain Alcohol. This is fine for baking as it'll all evaporate, but at that strength, it takes time to get out of an e-liquid. You can leave the cap off, but the longer the cap is off, the more potential for the flavor to diminish due to too much evaporation.
I've found that any more than 12 hours with the cap off and I can notice a flavor drop. After 24 hours, the flavor tends to really take a dive. This is based on going through probably 2-3 gallons of PG & VG and a ton of flavoring in the past 8 months with random experiments.
That said, vanilla extracts tend to extract the base oils in the caviar (vanilla bean seeds) and the flavor of the pod. This can be done with PG & VG instead of alcohol, but it takes quite a bit more time to impart the true flavor into mix than it would with alcohol. PG works as a pretty good solvent and it will extract flavor from a number of things. VG, IMO, isn't the best, but with a 50/50 blend or a 60/40 blend, you can get a decent extraction over the course of 30-90 days. Since vanilla is a fragile flavor, cold extraction works best. Heat can kill the flavor.