Welcome to ECF!
VTC5's are a 20A battery so the VTC4's are a better choice for above-20A vaping.
There are only two true 30A batteries, the LG HB6 and HB2. The best true 30A battery, in my opinion, is the LG HB6. But it's capacity is low, 1500mAh.
But, since your mod is dual battery, you could go with 20A rated batteries and enjoy the extra time between recharges. You could use the LG HG2 3000mAh battery which would last much longer than the HB6. While the HG2 relatively safe to use at 20A, no battery is "safe", it will run hotter than the HB6.
If you wanted the battery that ran the coolest no matter how hard you ran your ipv4, then the HB6 is the battery to get.