The high voltage attys are generally if you stack 2 3.7v batteries. That's going to deliver 7.4v which will pretty much burn out something like a 510 almost immediately. 2 3v batteries delivering 6v shortens 510 atty life significantly.
The measuring factor for vaping at different voltages should be watts which pretty much correlates to the heat produced. You're vaporizing liquid with heat so it's the temperature at the coil that counts. Too cool and there isn't much vaporization and too hot and it's burnt.
Watts is determined by voltage and resistance (assuming the power supply can supply infinite current -- a device "draws" current, it's not that a power supply "pushes" current). A normal Joye 510 atty presents a resistance right at 2.2ohms. When you apply 3.7v it generates about 6watts of heat. Most people find that the sweet spot for a 510 atty is right about 10.8watts. Max vapor without much burnt.
If all you happen to have is 2 3.7 batteries (and they work in your PV) and you want more than a single 3.7 vape you're going to need a 510 HV atty. The one that presents 5.2ohms of resistance instead of the regular one that presents 2.2ohms. If you applied 7.4v to a regular 510 (assuming it didn't instantly melt, which it probably would) you'd be generating about 23.8watts of heat. Instantly burnt juice. Apply 7.4v to a 510 HV atty (5.2ohms) and you'll be generating 10.5watts. Right there at the sweet spot same as 5v with a regular 510 atty. Another thing to note in this case is that 1 3.7v battery with a regular 510 atty produces about the same watts as 2 3.7v batteries with a 510 HV atty (5.2ohms). Same watts but twice the battery... the batteries should last about twice as long.
If you want more than 3.7v with a regular 510 but find that 6v (2x3v) is too hot you might want to try a 510 HV (the 4.5ohm one). That would be a heat range right inbetween the two.
You need to decide on the whole solution to get the end result you're after. Batteries and the atty that's going to work with them or visa versa. 510s, 801s, 901, HV versions all have a different resistance. With batteries you're pretty much fixed at 3v and 3.7v which can be stacked for 2x the voltage.
"High voltage juice"? I haven't heard of that... They weren't talking about heavy nicotine levels were they? I have found that some of my juices taste better at 3.7 than 5v and with others it's the opposite. 5v always give more vapor and a stronger hit.
Lot of personal preference involved with all the above.