Well, let's put it this way.
I smoke cigarettes.
I am smoking cigarettes.
I smoked.
I am a smoker.
VS
I vape electronic cigarettes.
I am vaping from my electronic cigarette.
I vaped.
I am a vaper, not raper.
Vaping came from the term vape. Vape is a derivation from the phrase "smoking electronic cigarettes" and we can call it the "internet jargon", not sure whether it is in the oxford dictionary yet but still, its origins came from electronic cigarettes. Thus, it is impossible to not associate vaping with cigarettes.
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In Psychological Context
As for whether the possibility of vaping will be disassociated with smoking, most probably and definitely a no. People smoke mostly because of the nicotine. Nicotine is present in vaping, but for some no. Thus, the common link in smoking and "smoking" (which is nicotine), is a strong one due to the fact that the primary and primary motive is to get a nicotine kick, which can be related to smoking. For instance, "I smoke ah need some nicotine." Thus, we can say that there's a direct association with "smoking" and smoking.
As for secondary motivation, we can link it to social needs (the likes of social smokers) and security needs; there's a common reason behind smoking and "smoking". The common ground aka motivations will already link them to each other on a secondary motive level. Example, Social Vaping VS Social Smoking. Example 2, "I need to smoke" or "I need to vape".
Also, the ideology of "smoke" c most oming out off your mouth will already associate it to smoking; for people, there is already sufficient evidence (the "smoke" coming out of your mouth) to prove that you are a smoker unless more knowledge about electronic cigarettes have been educated.
Example; if Person A does not know about vaping and sees "smoke" coming out of your mouth, the psychological link and connection to the stereotype and analogy of smoke itself will trigger Person A will interpret the "smoke" as cigarette/analog smoke. Therefore, you will be considered smoking to Person A.
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In Sociological Context
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Just some of my opinions that I was thinking about just a few nights before but these are related! Please don't flame me D: