What TommyG said. Parallel wiring is positive to positive and negative to negative. Parallel wiring gives you the same voltage at output as the individual batteries deliver, but more capacity in amperage and longer battery life before charge. Parallel shoudl deliver 3.7v dc to the load (atomizer).
Series wiring of batteries is additive in voltage, but the amperage delivery capacity will be less. You should get 7.4v dc from two 3.7v batteries wired in series.
A single battery mod with a boost circuit is much safer than a dual battery mod. Dual battery mods can experience a situation involving reverse charging where the battery with the higher charge can deliver current rapidly to the battery with the lower charge. Since this happens quickly, one battery can overheat and explode. This is what happens to the mods you have heard about where someone gets it in the face while vaping. It's not a pretty sight, I'm sure.
Lithium batteries contain a thick electrolyte. When it heats and expands, it does so at a rate that causes venting. When the venting occurs at a rate higher than the mod or batteries can expel, the result is that the batteries swell and explode and the mod itself can direct hot, caustic, thick liquid lithium outwards along with an explosive force. If you are vaping when that happens, you can imagine the result.
Protected batteries are designed to cut the circuit to the mod if overtemp or overcurrent occurs, that can be too late or the protection circuit could fail to act. The failure mode of IMR batteries is high heat, but they are not likely to vent vigorously or explode as protected batteries can. I'm leaning toward and using IMR these days.