Ok my OP sucked as a comparison, you guys are right actually. Let me try again to articulate myself.
Actually I shoulda known better. I transfer heat for a living and I do it all through propylene glycol, if anybody knows that was flawed it should be me.
This one boiling point I refer to, I don't believe it applies to the entire compound of eliquid. Eliquid is complex, it will fractionate and break up. That is, on a molecular level, different components if it's make up may boil at different temperatures. If you didn't atomize and instead just boiled, it would gradually break down into a little burned sludge pile.
But in atomizing were only concerned with that element that boils first, since that element carries everything else with it.
This is my uneducated understanding of that process- Liquid reaches the coil, having been dragged via capillary action. Once at the coil, the lowest layer of the thick e- liquid flashes to gas.
Because the liquid is so thick, the vapor particles must pass an outter layer of liquid as they violently expand and leave the coil. Vapor is much much larger then liquid.
As the vaporized bottom layer explodes through the upper layer, the upper layer mixes in and goes along for the ride.
So- the vapor particles contain heat from the coil (the heat that changed their state). This heat is quickly diluted however, by the cool liquid being carried by the vapor bubble.
The coil temperature stays in check because of the vapor, which carries off the heat. The process requires movement to continue, a steady supply of liquid. As eliquid leaves the coil it drags more behind it, a vacuum forms within the wick and through capillary action a supply of fresh liquid continues to bath the coil.
This is my uneducated take on atomizing. Nothing burns, it flashes and leaves.
Dry hit- If the coil temperature slips out of control (like, there's not sufficient juice flow to cool it) the whole process goes into a tailspin. Whole new animal. Without the volume of juice the coil cooling process dies, the coil temperature increases exponentially and rapidly, and juice flow stops.
That other element in the mix, the one that burns before it boils....that part has to fend for itself now. In atomizing, vapor was carrying that stuff off before it could reach burn temps but now it's laying there till it boils. By the time that stuff boils were in dry hit city.
So- when were atomizing we know it. When there is burning taking place we know it. There is not, IMO, this middle ground where it tastes like rich crisp juice but since our coil was too hot were being poisoned. We're atomizing or burning....