Your math looks right so, if you're set at 5V, it looks like you're either drawing more than 3.5 amps or you're only getting 3.74 volts. If you're drawing more amperage than what the device is engineered to output, I'd be worried.Let's see-> I * V = W = 3.5amps*5volts = 17.5 watts--> W * R = V^2 = 17.5watts * 0.8ohms = 3.74 volts
Something is not adding up....
PS Is there some reason why you're trying to run a sub-ohm coil on a PV that's not designed to do so?
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It fired at 4.5 Volts. 