It depends. In a series installation (one battery's positive touches the other battery's negative, like in a flashlight that runs on two AA batteries), you double the voltage. The mAh you have available remains the same, and the amperage you can draw remains the same as with one battery.
In a parallel (side by side with the batteries usually installed in the same direction) setup, the voltage remains the same at an average of 3.7, but your mAh doubles, as does the amps you can draw.
*Most* two battery mechanicals I've seen are in series...but not all.