Using a calculation I have seen (mah X C /1000) amps shouldn't be too much of a risk. one lifepo I saw (zippy 4200mah) it has a 30 constant C-rating.
so 4200 X 30 /1000 gives you a constant amp rating of 126 amps. and judging from the spec sheet on the DNA 200 it has a maximum current input of 23 amps the battery has pleeenty of room to survive.
meanwhile I am just wondering how the hell I am going to cut out the square hole for the screen.
LiFes are a very safe technology, so that's not an issue at all. And they can support a high discharge rate also. The issue for them is the full charge voltage is only 3.6v/cell (LiPos are 4.2v/cell). So if the DNA200 uses a conservative low voltage cutoff of 3.2v (I'm not sure what the LVC for the DNA200 is) it might not be able to use all it's available power. It is common to have a cutoff or 3.1 or 3.2v, so that really is going to be an important factor for how well LiFes do with this chip. Couple the LVC with the discharge curve of a LiFe cell, which starts out at 3.6v and drops pretty quickly to 3.2v where it stays for most of it's usable charge life and I'm just not sure it's going to perform well.
It's yet to be seen what the LVC of the DNA200 is, and that is probably the biggest concern I have with LiFe batteries with this chip. Maybe someone can chime that knows what the cutoff will be, and if it's settable in the software. LVC being settable to take advantage of LiFe battery technology, that differs quite a bit from LiPos, will be the deciding factor in how this battery tech will work I think. LiFes are designed to spend most of their time at 3.2v during a discharge cycle, so it's important the DNA200 can take advantage of this for LiFes to be viable. And even if the LVC cutoff is 3.1v, a nominal voltage of 3.2v on LiFes is going to trigger a LVC on the chip with normal voltage sag if vaping at high wattage, even though the LiFe pack is operating normally and within spec.
Just too early to say without knowing the complete specs of the DNA200, and seeing how much voltage drop occurs on a LiFe pack at high wattage vaping. I wouldn't be concerned at all about the LiFe pack being capable of doing the job, I just don't know If the DNA200 is smart enough to be able to use this different battery tech properly or if it just treats a LiFe pack as a LiPo pack... which would not be ideal.