Yes that is what I used to say too. As Kanthal is just iron-chromium-aluminium (FeCrAl) alloys. But this leaves some interesting questions. And I am not a welder or anything. But I always thought you can't weld aluminium to iron. They just don't mix.
Also heating Kanthal to a slight glow causes the aluminium to form a protective layer of aluminum oxide (alumina). But Kanthal only contains 4-7.5% of aluminium. If mixed, how would this be possible? Also we can do a science experiment. File or sand down one side of a piece of Kanthal, now try to form the alumina layer. If it doesn't form where it was filed, then the outer layer must contain aluminum and inside does not.
And why doesn't Kanthal rust (it contains over 60% iron)? Except when the center is exposed, now it rusts like crazy. Just like iron does.
I first thought that too. Until I realized the smell only comes from those Crown RBA coils. Every other dry burning I ever did (and I used to do many of them), never ever smelled anything like that. Here's another science experiment we can do. We can take a fresh unused Crown RBA coil (I still have some, I won't vape with them though) and heat it up and see if the same smell is there or not.
Sounds like you have some experiments to run Bill, but I'm 100% sure the kanthal is an alloy. The Fe and Al don't have to weld together to be alloyed together, the molecules are mixed/alloyed together but do not form a new compound.
Al oxidizes much easier, faster and at a lower temp than Fe or Cr. The Al molecules at the surface of the wire are the first to oxide (form Alumina) and the Al molecules deeper in the wire migrate to the outer wire surface through the boundary layers between the Fe and Cr molecules as the wire gets heated repeatedly. The more times the wire gets heated to red hot the more Alumina builds on the surface but the rate at which Alumina builds on the wire surface slows as the Alumina thickness.
Fe does not oxidize nearly as fast as Al when only exposed to ambient air (oxygen) but can oxidize quite quickly when exposed to water. I have rusted up my kanthal coils by quenching them under water while still glowing hot from a dryburn pulse.
ETA: Now if you're thinking that most of the Aluminum molecules in the wire migrate to the surface to form Alumina and leave the core of the wire as purer iron, no. The formation of Alumina on the wire surface is on microns thick and doesn't effect the wire's alloys more than jusy barely below the wire surface.
I'm not a Metallurgist Bill but have done extensive research on the formation of Alumina. Years ago there was a member on another thread that seemed to know everything about Kanthal and Alumina so I took his word for it at first, but after a while he was saying some really weird things and began contradicting himself. I took it upon myself to get to the bottom of it through internet research and lucky me, one of my father's cohorts was a NASA scientist who specialized in developing high heat resistant Alumina coatings in Jet engine nozzles. Anyways, I discovered that the member was a complete fraud.