I just measured my aw lifePO4 batteries right off the charger all 3 that say LifePO4 500 Mah 3.2 measure at 3.33. The one that just says LifePO4 500mah Measures at 3.80 and started dropping fast when testing to 3.79.
what charger are you using? i've seen 3.8V coming from the Tenergy charger before, but not from the Ultrafire WF-138A that Ikenvape carries. if you are using this charger, which you should be, are you making certain that the charger is set to 3V and not 3.6V. at the 3.6V setting the charger wants to charge the cell like a conventional lithium cobalt chemistry, 4.2V. because the chemistry of LiFePO4 batteries give mixed signals to a voltage detecting charger like that, it likely won't end up at 4.2, but could come off the charger at 3.8V or higher. all lifepo4 batteries have a nominal voltage of 3.2V and all of them should be charged up to 3.6V but never higher, most coming off the charger between 3.4 and 3.6. the only "3V" cell in that size (16340) is the Tenergy protected battery, that claims 900 mAh. that battery requires a special charger altogether to account for the diodes restricting the output voltage from a conventional lithium cobalt battery down to a 3V battery. wasted space in the circuitry and wasted energy as heat means even lower runtimes, which along questionable discharge specs amounts to a less than desirable battery for vaping. as others have suggested, if one of your cells is reading 3.8V throw it out. the chemistry of the battery is not suitable for charges that high, and exceeding the the maximum voltage like that can create more problems than simply blowing an atomizer.
stick with the AW LifePO4 batteries, use the Ultrafire WF-138A charger at the 3V setting, and continue to check voltages before and after charging. i think you'll be pleasantly surprised at their performance over time, and with attys at around 3.2Ω and slightly higher, you'll get a great vape and will seriously decrease the likelihood of popping atomizers that might not have fared as well otherwise at 6.4V off the charger and approximately 5.5V under load.