Pictures of serious battery failure - IMR 18650

Status
Not open for further replies.

rolygate

Vaping Master
Supporting Member
ECF Veteran
Verified Member
Sep 24, 2009
8,354
12,402
ECF Towers
Like Li-Mn they are a safe chemistry battery that is unlikely to blow up in your face. However there are two issues with Li-FePo4 cells:

1. Many of them are low quality and have a low C rating, meaning they cannot be safely used for atomizers as the current draw is over their limit. There are two groups of Li-FePo4 cells: those with a C rating of 1 (or less), and those with a rating of 4 and up. The C=1 cells will be over-driven by an atty: a Li-FePo4 14500 battery with a capacity of 600mAh and a C rating of 1 can supply 0.6 amps to an atty. This is too low and it will be over-driven. A cell of 600mAh with a C rating of 4 can supply 4 x 0.6 A = 2.4 amps, which is fine.

2. Almost all of them are 3 volt cells, not 3.7 volt cells, which means they cannot be charged in a normal lithium cell battery charger. This would charge them to a final voltage of 4.2 volts, way too high for these cells, and will damage them. Damaged cells are a good candidate for self-destructing.

Now imagine a scenario where a pair of low quality Li-FePo4 cells are overcharged in the wrong charger, then paired in a 6 volt mod, then asked to supply 2 amps+. This is a situation where unprotected Li-ion cells (or possibly, protected Li-ion cells where one of the protection circuits has failed) have blown up violently in the face of users when asked to deliver the first draws on an e-cig after coming off charge. It is my understanding that a Li-FePo4 cell will not explode in this situation but it will still fail and de-gas, just not as strongly as a Li-ion. The difference is just in the speed and volume of the gas produced. Maybe if the mod has no vents then things could be tricky.

No battery is safe when abused, but in theory Li-FePo4 and Li-Mn cells will not de-gas so violently that they are in effect exploding - but they will still burn up if mistreated badly enough.

Because of the two Li-FePo4 issues, it is safer to use Li-Mn cells in a mod. But even those cannot escape the consequences of mistreatment. They are very unlikely indeed to burn up without being mistreated in some way - so you need to check the off-charge voltage, use them in a mod with a master off switch and gas vents, and don't jam the mod in a pocket and leave it. The use of PCC cases for generic rechargeables currently has no history or safety record so may not be considered entirely safe at this time.
 
Last edited:

buGG

Ultra Member
ECF Veteran
Verified Member
Oct 10, 2009
1,486
227
brush²
Can someone with first hand knowledge of this please identify the various parts in the photos?

I'm not sure whether I'm looking at two batteries or just one, and if there is a dislocated nipple top from the 18650 in the images, whether there is a charred 510 atomizer and anodized aluminum drip tip in the picture or whether that's still in the car, and whether the metallic looking papers, also charred, are supposed to be the shrink wrap of the "IMR" cell(s) or something else entirely.

This incident would be a first, at least first reported for a LiMn chemistry battery from this manufacturer to have exploded and burned in what appears to have been a combustible scenario arising from a chemistry compound that contains very little oxygen and is widely reported to not vent with flames. So that alone makes it a unique opportunity to learn about what's really going on here, what we're all looking at, and what understanding we can actually come away with in terms of cell behavior and our actions.

I do think that the stated manufacturer and even the chemistry makeup of the cell should be removed from the title and/or from admin posts within the thread until or unless it is determined without a doubt that all is as it's being reported. At bare minimum, in a new member's thread, it could cause a very negative association that may later turn out to be unwarranted, unnecessarily fearful, or simply missing critical information that could better serve a new member in their decision-making process. Coming from forum users is one thing, but mods is simply another thing altogether.

At any rate, here's a couple threads from CPF that have dealt with similar issues, and some afford pics of what the cells look like after direct shorts. It might also be beneficial to supply the manufacturer with additional info, if not the forum at large, so that they can also respond and/or at least have an opportunity to identify the culprit, if any.

Link 1: RCR123A [LiCo]
Link 2: 18500 [LiMn]
Link 3: 26500 [LiMn]
 
Last edited:

slumdog

Super Member
ECF Veteran
Verified Member
Dec 15, 2010
884
309
South Florida & NYC The Village
the battery is a AW IMR

the only batt I will use.....Thanks for a great post OS! we have to stop thinking of these batts in terms of energizer or duracell....which can also explode but are less likely to do so unless used as we do......heat and battery's DO NOT MIX....be careful people the danger IS real... BUT definitely manageable with the right knowledge
 

Ronda

Full Member
May 21, 2011
36
8
Pa
I think relative risk is the thing to keep in mind. Most of us have been smoking analogs several times a day, sometimes in bed, always with a 700C (1292F) fire during draw. Treat your battery like a lit ciggy, and you'll be safer. Would you stick a lit cig in your pocket? Would you leave a lit ciggy burning when you went to bed? Would you set it on an unprotected surface? Relatively speaking, these are many times less likely to cause fire or damage to your person or property. Just my opinion.
 
You guys are plain wrong if you think lithium batteries are safe. Lifepo4 and li-mn are safer than li-co and li-po, but still ABSOLUTELY need cell level protection.

Endless-sphere.com • View topic - Liar Liar Pants On Fire > Thermal Runaway LifePO4 Ducktape

Here is a lifepo4 ebike battery that wasn't properly protected and caught fire.

People that use two separate batteries are playing with fire. Even with protection it still possible for fires and explosion if the batteries are used @ two separate states of charge.

People that store batteries loosely in a bag where they may turn on while something shorts them are putting themselves at risk.

Here is 177 incidences of lithium battery fires in the r/c community caused by defective cells and misuse.

Endless-sphere.com • View topic - Anyone thinking Lipo is safe needs to think again

This is dangerous stuff. Treat it with respect for the love of god!
 

APD99

Super Member
ECF Veteran
Verified Member
  • Mar 11, 2011
    305
    576
    Bristol, PA
    Here is 177 incidences of lithium battery fires in the r/c community caused by defective cells and misuse.

    I absolutely agree I've had ballooning issues and one catastrophic failure of a Li-Po even with no abuse, but it has given me good battery safety habits and ALL my batteries get charged in a Li-Po bag even my mod batts.
     

    masterace04

    New Member
    May 27, 2011
    3
    0
    37
    Glenwood Springs CO
    • Deleted by oldsoldier
    • Reason: spamming for post count not permitted
    Status
    Not open for further replies.

    Users who are viewing this thread