It's likely propylene glycol and vegetable glycerin residue. This won't accumulate in your lungs, because both propylene glycol and vegetable glycerin are 100% water soluble and hydrophilic, which means that there will be zero accumulation in any open system that is water based; e.g., your body. In other words, the propylene glycol and vegetable glycerin is quickly dissolved into your body and goes the way of all other metabolic waste. The EPA recently did a report on the toxicity levels of propylene glycol to re-certify it for use in air conditioning units and air purifiers. It found that there was no level of chronic toxicity, and that acute toxicity occurred in rats after they orally ingested 3,600 to 20,000mg per pound of body weight. It found no level of acute toxicity for skin or eye irritation, and stated 5 times that "there are no endpoints for concern for oral, dermal, or inhalation exposure to propylene glycol." I wrote up a summary here:
http://www.e-cigarette-forum.com/fo.../367917-safety-inhaling-propylene-glycol.html, which also contains a link to the original document issued by the EPA.
At any rate, since the atmosphere inside your car and inside your office are not water-based systems, there is no natural mechanism for dissolving buildup.
Incidentally, I've read that nicotine is absorbed more slowly with vapor than with smoking. If this is true, I have a theory to explain this: The nicotine is dissolved into a propylene glycol and vegetable glycerin base. This enters the lungs and takes several minutes to dissolve into the bloodstream, resulting in a delay of the nicotine absorption (as opposed to smoke, where the nicotine intake by the lungs is instantaneous).